Photocycloaddition of Benzoylated 2-Deoxyribonucleoside to 2,3-Dimethyl-2-butene.
نویسندگان
چکیده
منابع مشابه
Photochemistry of Cyclic Vicinal Tricarbonyl Compounds. Photochemical Reaction of 1,2,3- Indanetrione with 2,3-Dimethyl-2-butene: Hydrogen Abstraction and Photocycloaddition
A irradiação na região do ultravioleta de 1,2,3-indanotriona, em presença de 2,3-dimetil-2buteno, em diclorometano, leva a uma mistura complexa de produtos formados a partir de reações de abstração de hidrogênio, fotocicloadição [2π+2π] (reação de Paternò-Büchi) e fotocicloadição [4π+2π]. A distribuição de produtos é dependente de fatores eletrônicos e estéricos, com estes últimos sendo os resp...
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In the title compound, C(15)H(15)NO(4), the quinoline ring system and one of the malonate side chains are essentially coplanar (r.m.s. deviation = 0.0297 Å). The two malonate C-C(=O)-O-CH(3) side chains are oriented at right angles [89.68 (8)°] with respect to each other. The crystal packing is stabilized by weak non-classical inter-molecular C-H⋯O hydrogen bonds, which link the mol-ecules into...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1995
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.43.144